Astronomers using data from the NASA/ESA/CSA James Webb Space Telescope have identified carbon dioxide in a specific region on the icy surface of Europa. Analysis indicates that this carbon likely originated in the subsurface ocean and was not delivered by meteorites or other external sources. Moreover, it was deposited on a geologically recent timescale. This discovery has important implications for the potential habitability of Europa's ocean.

"On Earth, life likes chemical diversity - the more diversity, the better. We're carbon-based life. Understanding the chemistry of Europa's ocean will help us determine whether it's hostile to life as we know it, or whether it might be a good place for life," said Geronimo Villanueva of NASA's Goddard Space Flight Center in Greenbelt, Maryland, lead author of one of two independent papers describing the findings.

"We now think that we have observational evidence that the carbon we see on Europa's surface came from the ocean. That's not a trivial thing. Carbon is a biologically essential element," added Samantha Trumbo of Cornell University in Ithaca, New York, lead author of the second paper analysing this data.

A surface-ocean connection
Webb finds that on Europa's surface, carbon dioxide is most abundant in a region called Tara Regio - a geologically young area of generally resurfaced terrain known as 'chaos terrain'. The surface ice has been disrupted, and there has likely been an exchange of material between the subsurface ocean and the icy surface.

"Previous observations from the Hubble Space Telescope show evidence for ocean-derived salt in Tara Regio," explained Trumbo. "Now we're seeing that carbon dioxide is heavily concentrated there as well. We think this implies that the carbon probably has its ultimate origin in the internal ocean."

"Scientists are debating to what extent Europa's ocean connects to its surface. I think that question has been a big driver of Europa exploration," said Villanueva. "This suggests that we may be able to learn some basic things about the ocean's composition even before we drill through the ice to get the full picture."

Both teams identified the carbon dioxide using data from the integral field unit of Webb's Near-Infrared Spectrograph (NIRSpec). This instrument mode provides spectra with a resolution of 320 x 320 km over a field of view of diameter 3128 km on the surface of Europa, allowing astronomers to determine where specific chemicals are located.

Carbon dioxide isn't stable on Europa's surface. Therefore, the scientists say it's likely that it was supplied on a geologically recent timescale - a conclusion bolstered by its concentration in a region of young terrain.

"These observations only took a few minutes of the observatory's time," said Heidi Hammel of the Association of Universities for Research in Astronomy, a Webb interdisciplinary scientist leading Webb's Cycle 1 Guaranteed Time Observations of the Solar System. "Even in this short period of time, we were able to do really big science. This work gives a first hint of all the amazing Solar System science we'll be able to do with Webb."

Searching for a plume
Villanueva's team also looked for evidence of a plume of water vapour erupting from Europa's surface. Researchers using the NASA/ESA Hubble Space Telescope reported tentative detections of plumes in 2013, 2016, and 2017. However, finding definitive proof has been difficult.

The new Webb data show no evidence of plume activity, which allowed Villanueva's team to set a strict upper limit on the rate at which material is potentially being ejected. The team stressed, however, that their non-detection does not rule out a plume.

"There is always a possibility that these plumes are variable and that you can only see them at certain times. All we can say with 100% confidence is that we did not detect a plume at Europa when we made these observations with Webb," said Hammel.

These findings may help inform NASA's Europa Clipper mission, as well as ESA's Jupiter Icy Moons Explorer, Juice, which was launched on 14 April 2023. Juice will make detailed observations of the giant gas planet and its three large ocean-bearing moons - Ganymede, Callisto and Europa - with a suite of remote sensing, geophysical and in situ instruments. The mission will characterise these moons as both planetary objects and possible habitats, explore Jupiter's complex environment in depth, and study the wider Jupiter system as an archetype for gas giants across the Universe.

"This is a great first result of what Webb will bring to the study of Jupiter's moons," said co-author Guillaume Cruz-Mermy, formerly of Universite Paris-Saclay and current ESA Research Fellow at the Agency's European Space Astronomy Centre. "I'm looking forward to seeing what else we can learn about their surface properties from these and future observations."

"The results reinforce the importance of the Juice mission," continues Guillaume. "With its MAJIS instrument, Juice will make it possible to observe the same surface over the same range of wavelengths but at a much greater spatial resolution and over a longer period of time, and therefore will further constrain the habitability condition of Europa."

The two papers associated with this research will be published in Science on 21 September 2023.

Full caption
This graphic shows a map of Europa's surface with NIRCam (Near Infrared Camera) in the first panel and compositional maps derived from NIRSpec/IFU (Near Infrared Spectrograph's Integral Field Unit) data in the following three panels.

In the compositional maps, the white pixels correspond to carbon dioxide in the large-scale region of disrupted chaos terrain known as Tara Regio (centre and right), with additional concentrations within portions of the chaos region Powys Regio (left). The second and third panels show evidence of crystalline carbon dioxide, while the fourth panel indicates a complexed and amorphous form of carbon dioxide.

Astronomers using Webb have found carbon on the chaos terrain of Tara Regio and Powys Regio. Surface ices in these regions have been disrupted, and there has likely been a relatively recent exchange of material between the subsurface ocean and the icy surface.

Carbon, a universal building block for life as we know it, likely originated in Europa's ocean. The discovery suggests a potentially habitable environment in the salty subsurface ocean of Europa.

The NIRSpec/IFU images appear pixelated because Europa is 10 x 10 pixels across in the detector's field of view.

Related Links
Webb Telescope at ESA
The million outer planets of a star called Sol